Super Friends (1973)
S1E12 The Menace of the White Dwarf
Episode Overview
An unusual UFO breaches Earth's atmosphere, capturing various items in its wake. Col. Wilcox informs the Super Friends that the craft has seized an astounding 14,000 tons of material. Meanwhile, Superman discovers that his longtime foe, Raven, is orchestrating these bizarre events. The sinister scientist has broken free from incarceration, intent on exacting his vengeance.
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S1